Distinct molecular dynamics dividing liquid-like and gas-like supercritical hydrogens
نویسندگان
چکیده
By finding that intramolecular properties and smearing dynamics of a solvation shell exhibit the anomalous order crossing Widom line, we demonstrated supercritical fluid is mixture liquid gas possessing heterogeneity.
منابع مشابه
The Widom line as the crossover between liquid-like and gas-like behaviour in supercritical fluids
According to textbook definitions1, there exists no physical observable able to distinguish a liquid from a gas beyond the critical point, and hence only a single fluid phase is defined. There are, however, some thermophysical quantities, having maxima that define a line emanating from the critical point, named ‘the Widom line’2 in the case of the constant-pressure specific heat. We determined ...
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2021
ISSN: ['1463-9076', '1463-9084']
DOI: https://doi.org/10.1039/d1cp02650j